It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries. So this ferritic stainless steel is immune to stress corrosion cracking. Metals like stainless steels and aluminum contain elements such as niobium and chromium, often integrated because of their natural corrosion resistance. Intergranular corrosion and stress corrosion larissacglima. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion. Intergranular stress corrosion cracking resistance of. Fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel. Intergranular cracking proceeds along the grain boundaries whereas transgranular cracking does not have preferences for boundaries 69. This form of corrosion cracking is caused by a combination of tensile stresses on the material in the presence of corrosive conditions. The factors of hydrogen embrittlement and ways to prevent it is.
Fully intergranular cracking was obtained in the 20% deformed, nonsensitised aisi 316ng stainless steel in simulated bwrenvironment. In this chapter, the conditions for the occurrence of scc are first introduced. The photos above show the microstructure of a type 304 stainless steel. Intergranular corrosion occurs in certain grades of stainless steel when the steel is heated, as in welding. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. It is a fracture that follows the grains of the material.
Intergranular stress corrosion cracking of austenitic stainless steel piping in bwrs has been a. Transgranular stress corrosion cracking of 304l stainless. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. What alloys are prone to sensitization and how to avoid it. This occurs at temperatures between about 450850 c. Different kinds of corrosion on stainless steel montanstahl.
It explains how hydrogen embrittlement occurs in stainless steel. The mechanical properties of stainless steel are what allows stainless structures to remain the most resistant to rust. To understand intergranular corrosion testing or intergranular attack commonly abbreviated as igc or iga, it is important to understand what causes the process to occur. Mar 28, 2016 intermetallic compound such as mg5 al8,formation at the grain boundaries form a galvanic cell with a alloy matrix and in chloride environment severe intergranular type of corrosion occur. Titanium, niobium, and their carbides dissolve in steel at very high temperatures. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Intergranular fracture is the propagation of cracks along the grain boundaries of a metal or alloy. Corrosion of stainless steels stainless steels coursera. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
Intergranular attack of steel by molten copper depending on the composition and crystal structure of steel being surfaced with copper, stresses resulting from surfacing under a welding arc together with cu penetration of steel grain boundaries can result in open cracks of significant size under the cu deposit. For ferritic stainless steel, the cause of intergranular corrosion is precipitation of chromium nitride as well as chromium carbides. The consequence of igo and the concentration gradients that develop during oxide formation is that the material adjacent to. In austenitic stainless steels, titanium or niobium can react with carbon to form carbides in the heat affected zone haz causing a specific type of intergranular corrosion known as knifeline attack. Intermetallics segregation at grain boundaries in aluminum alloys also causes intergranular corrosion but with a different name exfoliation. This presentation is given to the members of steel founders society of america in order to serve as a framework which can be used to identify the cause of cracks in steel castings. You can avoid pitting corrosion by ensuring that stainless steel does not come into prolonged contact with harmful chemicals or by choosing a grade of steel which is more resistant to attack. Intergranular attack is caused by the formation of chromium carbides fe,cr23c6 at grain boundaries, reducing the chromium content and the stability of the passive layer on stainless steels. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. And this diagram is sometimes called the copsoncurve. Intergranular corrosion facts and how to reduce the risk. Intergranular corrosion stainless steel tubing manufacturer. Austenitic stainless steels are normally ductile and exhibit deep dimples on fracture surfaces. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning.
Though steel is pretty strong a material and is considered in most of the construction works and in the making of almost all of our household materials, it might also develop cracks at times. Intergranular corrosion of stainless steel often occurs after an incorrect heat treatment, and the heat treatment that causes the intergranular corrosion tendency of stainless steel is called sensitization heat treatment. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Intergranular oxidation igo intergranular attack iga. Intergranular corrosion igc can seriously weaken the bonding force between crystal grains and the mechanical strength of metals and alloys would be markedly damaged due to igc.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking behavior of nickel base alloys. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. At some cooling regimes depending on the rate of cooling. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Due to the low solubility of nitrogen in ferritic stainless steels, the depletion of chromium can be caused by the precipitation of chromium nitrides as well. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Brittleness results, causing the metal to crack near the weld. If the carbon level in the steel is too high, chromium can combine with carbon to form chromium carbide. The chromium depleted zone becomes the preferential path for corrosion attack or crack propagation if under tensile stress. Intergranular corrosion of nonsensitized austenitic stainless. Even with the best maintenance procedures and preventative maintenance techniques, problems can still arise.
The chief reasons for using duplex stainless steels are their good resistance to oxidation, corrosion, and stress corrosionall this while maintaining superior. Intergranular fracture failure analysis and prevention failure. Corrosion and corrosion properties of stainless steels. Grainboundary strengthening is characteristic of ig fractures caused by embrittlement. Intergranular stress corrosion cracking in rbmk reactors to assist countries operating rbmk reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping.
Also, an en vironment that causes scc in one alloy may not cause it in another. Characterization of intergranular stress corrosion cracking of 304. Chromium carbides can be precipitated if the stainless steel is sensitized in the temperature range 550850c 10201560f, for example during heat treatment or welding. The effects of nitrate on the stress corrosion cracking of.
How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. The sensitization heat treatment range of austenitic stainless steel is 450 c 850 c. By decreasing the nickel content, we can obtain ferritic stainless steel. What forms of corrosion can occur in stainless steels. Intergranular attack in welded stresscorrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. Intergranular corrosion igc intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Axial corrosion fatigue was mainly driven by hoop stresses from internal operating pressures and corrosion. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking. Cracks initiated at intergranular corrosion penetrations propagating by corrosion assisted fatigue.
Figure 3 shows two microstructures of type 304 stainless steel. This type of corrosion was previously a potential risk for stainless steel because of its high carbon content. Steam turbines are used across the world as a source of power for many different industries. Feb 06, 2011 intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated. The combination of stress and igc, for some alloysenvironment systems will cause intergranular stress corrosion cracking igscc zhou and zuo, 2015. Stainless steel is one of the most common materials that suffer from this type of corrosion. What is intergranular stress corrosion cracking igscc. The chromium available to form the passive layer is effectively reduced and corrosion can occur. Grainboundary carbide precipitation in austenitic stainless steels sensitization. Intergranular stress corrosion cracking igscc is more common than transgranular scc. The consequence of igo and the concentration gradients that develop during oxide formation is that the material adjacent to the oxides has modified transformational behavior. Cracking of stainless steel nozzle sleeve metallurgical.
The interaction of corrosion fatigue and stresscorrosion. The influence of surface finish on crack initiation is also discussed. Igo is a surface phenomenon that is most often associated with atmosphere gas carburizing fig. These steels can, however, exhibit brittle intergranular fracture. Intergranular corrosion for stainless steel corrosion. Igscc of bwr low carbon and stabilized stainless steels, late 1980s. Reheating a welded component during multipass welding is a common cause of this problem. For example, ig fatigue failure in austenitic stainless steels usually occurs.
Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Iga is only of concern with austenitic stainless steels when the material is subject to caustic or halide solutions as from improper chemical cleaning or water treatment. Pdf intergranular stress corrosion cracking behavior of. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. This article explains all about hydrogen embrittlment in stainless steel. Stainless steel requires a supply of oxygen to make sure that the passive layer can form on the. Intergranular stress corrosion cracking of welded steel twi. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. Intergranular corrosion intergranular corrosion iga is a form of localized corrosive attack of areas adjacent to the grain boundaries. Nicrmo alloys were attacked by induced cracking in media of super critical water oxidation.
It is also explained that how to test the damage due to hydrogen embrittlement in stainless steel. It appears that stress corrosion cracking in austenitic stainless steels in the. Overview of intergranular fracture of neutron irradiated austenitic. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Sep 07, 2019 though steel is pretty strong a material and is considered in most of the construction works and in the making of almost all of our household materials, it might also develop cracks at times. Scc in a 316 stainless steel chemical processing piping system. Intergranular attack in welded stresscorrosion resistant. Intergranular stress corrosion cracking an overview. Transgranular, granulated, and intergranular stress corrosion. This process is also called sensitisation and typically occurs during welding. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion. Crevice corrosion stainless steel requires a supply of oxygen to make sure that the passive layer can form on the surface. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Intergranular corrosion can occur in many alloys systems such as stainless steel, nickel base and aluminum base alloys. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the. So stress corrosion cracking resistance of stainless steel is obtained by lowering or just adding very high nickel. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the alloy to be susceptible to intergranular corrosion. Chlorides will not cause scc unless an aqueous phase is present. Pdf intergranular cracking of aisi 316ng stainless steel in. Transgranular stress corrosion cracking of 304l stainless steel pipe clamps in direct use geothermal water heating applications m. In very tight crevices, it is not always possible for the oxygen to gain access to the stainless steel surface thereby causing it to be vulnerable to attack. Intergranular attack is also a quite rare form of corrosion.
Hurley boise state university 1910 university drive boise, idaho 837252075 c. Olson boise state university 1910 university drive boise, idaho 837252075 l. In the case of transgranular scc, the cracks advanced across the specific crystal planes with low indices 70. Intergranular fractures travel along the grain boundaries, rather than through the actual grains. Stainless steels are more resistant to general corrosion compared with carbon steel.
It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Resolving one of the more serious issues, that of stress corrosion cracking, can often be achieved in a straightforward manner by accurately identifying the causes. Another related kind of intergranular corrosion is termed knifeline attack kla. Stainless steel contains a fine layer of chromium oxide that when breached or broken include natural techniques to selfrepair. Circumferential corrosion fatigue cracking was mainly driven by thermal stress cycles and corrosion. Intermetallic compound such as mg5 al8,formation at the grain boundaries form a galvanic cell with a alloy matrix and in chloride environment severe intergranular type of corrosion occur. Reasons for intergranular cracking in the cases considered include i. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking.
Pdf stress corrosion cracking of stainless steel components. This was caused by the small sample sizes, which gave fairly slow cooling and hence. Some of the shallow intergranular penetrations were driven to significant depths due to corrosion fatigue. Intergranular stress corrosion cracking igscc is defined as cracking that occurs along the grain boundaries of crystallites due to corrosion. Dec 19, 2019 intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. However, with modern steel making methods, it has become possible. Possible causes for granulated cracking and its relationship to transgranular and intergranular cracking are discussed. Intergranular fracture failure analysis and prevention. For this reason, a postweld heat treatment is needed before reinstalling stainless steel parts that have been welded. The crack growth data and the mechanism are discussed based. Sep 04, 2018 intergranular fracture is the propagation of cracks along the grain boundaries of a metal or alloy. Elements of corrosion damaging stainless steel stainless. Effect of temperature in hydrogen embrittlement in stainless steel, and fusion in inox steel. Knifeline attack impacts steels stabilized by niobium, such as 347 stainless steel.
Grainboundary strengthening is characteristic of ig fractures caused. Transgranular and intergranular cracking have been reported before, but granulated cracking has not. Some of these stress corrosion cracks have caused major ruptures in gas and oil. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Changing the temperature, the degree of aeration, andor the concentration of. It has been observed that hastelloy c276 and inconel 625 are attacked by intergranular cracking when subjected to different aqueous solutions in the region of critical point of water at 374oc.
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